Synthesis of a bicyclobutane fatty acid identified from the cyanobacterium Anabaena PCC 7120.
AUTHORS
DeGuire
SMSean M ,
Ma
S Shutao ,
Sulikowski
GA Gary A .
Angewandte Chemie (International ed. in English). 2011 10 10; 50(42).
9940-2
- PMID: 21898738[PubMed].
- PMCID: PMC4096701.
- NIHMSID: NIHMS589071
ABSTRACT
By design: a carbanion-mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide.
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
By design: a carbanion-mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide.
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.