Synthesis of a bicyclobutane fatty acid identified from the cyanobacterium Anabaena PCC 7120.

Authors

DeGuire SM Sean M , Ma S Shutao , Sulikowski GA Gary A .
Angewandte Chemie (International ed. in English). 2011 10 10; 50(42).
9940-2

Abstract

By design: a carbanion-mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide.

Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


By design: a carbanion-mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide.

Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.