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Modulating aggregation-induced emission via a non-conjugated linkage of fluorophores to tetraphenylethenes


AUTHORS

Han X. , Zhang B. , Chen J. , Liu S.H. , Tan C. , Liu H. , Lang M.J. , Tan Y. , Liu X. , Yin J, . J. Mater. Chem. B. 2017 ; 5(). 5096-5100

ABSTRACT

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A fluorophore consisting of two fluorescent moieties could display unusual optical behaviors that are unattainable in a single-fluorophore compound. Herein we reported two “dual-fluorophore” dyes: DNS-linked tetraphenylethene demonstrates bright aggregation-induced emission, while NBD-linked tetraphenylethene exhibits aggregation-caused quenching. Our results have important implications for engineering emission behaviors of molecular aggregates for practical applications.

Graphical abstract: Modulating aggregation-induced emission via a non-conjugated linkage of fluorophores to tetraphenylethenes